I am looking at getting a new steering wheel of my 07 plate octavia vrs and was wondering if the is any with steering wheels controls I could use 

You can.

But there are a few stumbling blocks.

Most second hand steering wheels are sold without airbags, so it's easiest to find a steering wheel that has the same shape as your current one so you can use your existing airbag.

 

To make the buttons work, you may need to change the clockspring/controller as well, depending on what is currently fitted. Some work only to pass on the horn and airbag signals, some have the steering angle sensor, some have maxidot compatibility, some have phone/radio connection and some cruise control. And all possible combinations of the above..

Then it will need to be coded to the car with vcds.

You may also need a little additional wiring but I'm not sure.