096 is the biggest case size..there is no "upper limit" on Ah capacity.
Yes you need to alter the settings..if its the exact same battery Ah, type just alter the serial number setting by one digit...if its different Ah or type then these settings also need altering
All info in my previous posts, but I'll repeat:-
This is from I how to guide I did on the MK7 Golf forum..same applies for any MQB platform car like the Mk3 Octavia..
How to retro-fit a bigger capacity battery to a Mk7 Golf | GOLFMK7 - VW GTI MKVII Forum / VW Golf R Forum / VW Golf MKVII Forum
VCDS coding required
From the Main screen:-
Select Control Module [Select]
[19-CAN Gateway]
Advanced Functions screen:-
[Adaptions-10]
New value choice screen:-
Change the following four channels, inputting the relevant data about the new battery.
IDE03256-MAS06105-Battery adaptation-Rated battery capacity
IDE03256-MAS06106-Battery adaptation-Battery technology
IDE03256-MAS06107-Battery adaptation-Battery manufacturer
IDE03256-MAS06108-Battery adaptation-Battery Serial Number
When you click on "Battery technology" (using VCDS 21.3.0) a drop down list appears with the following options (= actual meaning):-
Wet = Standard Lead Acid
Fleece = Standard A.G.M.
Wickel6V
Wickel12V
Ultracap
Gel = Standard Gel Lead Acid
Lithium ions = Standard LiFePO4
EFB = Standard E.F.B.
Binary - AGM = "Bipolar" A.G.M. type
EFB+ = E.F.B. "Plus" type
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Not_assigned_11
Not_assigned_12
Not_assigned_13
Not_assigned_14
Unknown
According to various sources of information, including numerous car scans & threads on Ross-Tech, "Fleece" is for standard AGM batteries, "EFB" is for standard EFB batteries, & "Wet" is for standard lead acid batteries, as these settings are used at the factory. The setting of "Binary - AGM" is apparently for specialist "Bipolar AGM" batteries! Also the drop down list is from VCDS & not generated by your car's BCM, therefore, your car may not support all the options on the list, & the BCM will reject the value when you tell it to accept it!
Battery BEM codes are now redundant with the above separate channels. The most important channels are:- Rated battery capacity, Battery technology, & Battery Serial Number. For the Battery Serial Number, just change one digit of the old one. This channel tells the BCM that a new battery has been installed & to relearn the new battery & forget any “learnt values” for the old battery!